1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate
نویسندگان
چکیده
In the title compound, [Co(C(13)H(22)P)(2)]PF(6), the Co(III) atom is sandwiched between two (diisobutyl-phosphino)cyclo-penta-dienenyl ligands. The two diisobutyl-phophine units are trans to each other with respect to the Co(III) metal center. The PF(6) (-) anion links the cobaltocenium cations via weak C-H⋯F hydrogen bonds into a chain running along the b axis. The chains are further linked by C-H⋯F hydrogen bonds, forming a layer extending parallel to the (10) plane.
منابع مشابه
[1,1′-Bis(diphenylphosphino)cobaltocenium-κ2 P,P′]dichloridoplatinum(II) hexafluoridophosphate
The title bimetallic compound, [PtCl(2){Co(C(17)H(14)P)(2)}]PF(6), was obtained by reaction of 1,1'-bis-(diphenyl-phosphino)cobalto-cenium hexa-fluorido-phosphate with bis-(acetonitrile)di-chloridoplatinum. The Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two P atoms of the 1,1'-bis-(diphenyl-phosphino)cobaltocenium moiety and two Cl atoms. In the crystal ...
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