1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate

نویسندگان

  • Jian-Guo Hou
  • Ding-Biao Li
  • Man-Zhen Qiu
چکیده

In the title compound, [Co(C(13)H(22)P)(2)]PF(6), the Co(III) atom is sandwiched between two (diisobutyl-phosphino)cyclo-penta-dienenyl ligands. The two diisobutyl-phophine units are trans to each other with respect to the Co(III) metal center. The PF(6) (-) anion links the cobaltocenium cations via weak C-H⋯F hydrogen bonds into a chain running along the b axis. The chains are further linked by C-H⋯F hydrogen bonds, forming a layer extending parallel to the (10) plane.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008